几何优化
Calculations including geometry optimization and vibrational analysis for the stationary points on the ground and the first excited states were performed.
对基态和第一个三重激发态反应途径上所有中间体和过渡态进行了几何结构优化和频率计算。
In the second case, after failure to obtain the optimized TS by standard methods, the starting structures for all the TS optimizations were obtained from equilibrium geometry optimization technique along their reaction coordinates.
第二个例子是在使用标准过渡态优化方法失败后,根据物理问题从反应途径上用平衡几何构型优化方法选择过渡态优化的初始结构;
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